Hi guys, after some help from the kind members of this form, my first batch of gold refining went well using AP and the clorox method.
I have now managed to find a source of nitric and began using this for my second batch.
I placed 15 smashed processors in an equal mix of water and 70% nitric. I did this outside and then left the scene until the brown gas was gone.
I got a dark green solution, poured this off through a filter into another bottle and placed a copper pipe in the filtered solution to recover the silver. I also put some of the same dark green filtered solution in another bottle with no copper pipe. The processors were releasing their gold flakes, and I put a small amount more nitric + water on the processors & gold flakes to make sure all base metals get dissolved and left the three containers overnight.
The next day the liquid that the processors & gold flakes were in was only a light green so I assumed all base metals had been dissolved. I filtered off the light green liquid and kept it for silver recovery again.
I was surprised to find that the two bottles with the filtered dark green liquid from the previous day had now turned a light blue. The one with the copper pipe in had some silver powder at the bottom so I filtered this off and kept it to dry out. Any ideas why the solution turned from green to blue?
I then did a few water washes on the processors + gold flakes and covered them with HCL. I added a few drops of nitric until the gold flakes started to dissapear. I then left this overnight.
The next day the solution was dark green. So it seems there were more base metals that hadn't dissolved and I needed to do more acid washes or longer acid washes before using AR. I will remember that for next time. The gold flakes have dissapeared so I have those in solution too.
I was just wondering what the best method would be from here. It seems I have two options:
Place a copper pipe in this solution which will cement out the gold and silver. I can then decant and filter out the silver & gold powder, dissolve the silver with some nitric, and then filter and refine the gold powder with AR. I can also cement the silver back out of the filtered solution using copper pipe again.
The second option would be to drop the gold using SMB, filter it out and then go after the silver with copper pipe.
Or if there is another method that you guys can think of I am happy to hear.
Thanks
I have now managed to find a source of nitric and began using this for my second batch.
I placed 15 smashed processors in an equal mix of water and 70% nitric. I did this outside and then left the scene until the brown gas was gone.
I got a dark green solution, poured this off through a filter into another bottle and placed a copper pipe in the filtered solution to recover the silver. I also put some of the same dark green filtered solution in another bottle with no copper pipe. The processors were releasing their gold flakes, and I put a small amount more nitric + water on the processors & gold flakes to make sure all base metals get dissolved and left the three containers overnight.
The next day the liquid that the processors & gold flakes were in was only a light green so I assumed all base metals had been dissolved. I filtered off the light green liquid and kept it for silver recovery again.
I was surprised to find that the two bottles with the filtered dark green liquid from the previous day had now turned a light blue. The one with the copper pipe in had some silver powder at the bottom so I filtered this off and kept it to dry out. Any ideas why the solution turned from green to blue?
I then did a few water washes on the processors + gold flakes and covered them with HCL. I added a few drops of nitric until the gold flakes started to dissapear. I then left this overnight.
The next day the solution was dark green. So it seems there were more base metals that hadn't dissolved and I needed to do more acid washes or longer acid washes before using AR. I will remember that for next time. The gold flakes have dissapeared so I have those in solution too.
I was just wondering what the best method would be from here. It seems I have two options:
Place a copper pipe in this solution which will cement out the gold and silver. I can then decant and filter out the silver & gold powder, dissolve the silver with some nitric, and then filter and refine the gold powder with AR. I can also cement the silver back out of the filtered solution using copper pipe again.
The second option would be to drop the gold using SMB, filter it out and then go after the silver with copper pipe.
Or if there is another method that you guys can think of I am happy to hear.
Thanks