To avoid pipes from forming in the mold when pouring pour Au, keep the flame at the mold then slowly turn off your flame while it is being directed to the mold.
Pipes form from rapid cooling. If you are able to do this successfully you will have a pure gold bar without a pipe.
I do believe you still want to make pure Ag bars. As for cleaning the mold, I'm not sure how to do it with graphite, check for graphite hardness and use the material next to its hardness. Scrub that material into the graphite mold with soap and water multiple times.
I'm only using steel molds btw. I would love to see your pure Au bar poured in a graphite mold.