Hello,
This comes from my book; Fire Assay, by Orson Cutler Shephard and Waldemar F. Dietrich Copy right 1940: Portland cement alone is sometimes used for assay cupels; it is more commonly used with various percentages of bone ash. When cement is used as all or part of the cupel composition the amount of mixing water should be 8 to 12 per cent. Less or more cause the cement to check or crack on heating. Pure cement cupels give higher cupellation loss than do bone ash cupels, but mixtures of cement and bone ash up to 75% cement give as low a percentage of losses as those made of pure bone ash. Have fun!
P.S. It took me two years to puzzle out how to perform a fire assay. I found this book in a Colorado used book store about four years after (I thought), mastering the process. This book has helped greatly, is probably one of the books you'll never find in the library, and goes into fire assay with such scope and depth that I feel overwhelmed.