I'd bet Irons is right.
You might have a little gold mine there, assuming gold was what they mainly dealt with. If silver was the main or only metal, it's only worth 1/63 of gold, for the same amount, and I would probably forget it. Try to think like a miner. Depends on what they made, how much they made of it, what they made it out of, and how clean and tidy their operation was. Everyplace in that building probably has gold in it - dust, floors and walls, cracks and crevices, sludge, carpets, drain traps, wooden floors, etc., etc. Can you explain that room where the fume hoods are in more detail? Is it possible they were refining in there? Any equipment in the building? What kind of jewelry did they make - gold or silver or both? Are there any dried up containers? Post some photos of the various rooms?
If the plating room has wooden floors, I would probably burn some of them and get the gold from the ash. If you can figure out where the gold plating was done, the boards in that area should have more gold.
In the late 60's/early 70's, Harlyn Products, a big old jewelry manufacturer in the L.A. jewelry district (Hill Street area), shut their doors. The small refining room was all wood - floor, ceiling, and walls. They incinerated the wood and supposedly got $30,000 worth of gold, at $42/oz - about $1 million today. After this, I hired a guy that worked in the Harlyn refinery and trained him to be my fire assayer. That's how I know what happened over there. We worked together for about 15 years in several different places. He worked for me about 7 years - then we worked together for about 8. Harlyn is where the infamous George Gadja worked and "learned?" his trade, by the way.
The first thing I would do is get someone in there with an XRF gun, a good one, well setup for precious metals. It will tell you, at least, if gold is present or not. The actual % numbers it gives are not that accurate except for, maybe, comparison. For example, I would collect a pinch here and a pinch there of dust from the same basic area, mix it, and shoot it several times - takes 30 sec per shot. Same with sludge - I might dry the pile of amalgamated small pinch (or, spoonful or pipe samples) samples first, before shooting. Actually, the best way to sample sludges or powders is to drive a pipe (say, 1/2" or 5/8" ID) to the bottom a couple of different times and remove the material from the pipe. Put some Vicks under your nose when dealing with traps. In a few hours, a lot of your questions will be answered. The best way is to ultimately have the samples fire assayed. However, XRF will help you decide on what to take and what to leave.
When sampling anything, your goal is to do intelligent things so the total sample is representative in value of the total lot of that particular type of material. One simple "grab" sample is somewhat worthless. Think about what you're doing. It's really pretty simple, yet very important.
After all this, all you have to do is deal with a refiner and try to keep from getting cheated.