Could be due to a type of coating that the manufacturer put on the PCBs, or the flux they used, possibly even an accidental drip of fluorocarbon oil got on there during the manufacturing process.
I worked manufacturing electronics for 13 years. The moisture resistant coating we applied to the boards kind of had a cake baking smell to them when hot.
Some of the fluxes we used smelled sweet.
Fluorocarbon oil also smells very sweet when over heated. The reason fluorocarbon oil may be used some times in electronics manufacturing is because it will not conduct electricity. So if accidentally dripped on the boards there is no worry of shorting it out.
But no matter the source, you have already received the best advice, if it has an odor its probably best not to breath it..