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Below is the MSDS Sheet for Stannous Chloride.
Material Safety Data Sheet
Tin (II) Chloride, Anhydrous, 98%
ACC# 01563 Section 1 - Chemical Product and Company Identification
MSDS Name: Tin (II) Chloride, Anhydrous, 98%
Catalog Numbers: AC196980000, AC196980250, AC196981000, AC196985000
Synonyms: Stannous chloride anhydrous; Tin dichloride; Tin protochloride
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
7772-99-8 Stannous chloride 98 231-868-0
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: white crystals. May cause severe eye irritation and possible injury. Causes severe respiratory tract irritation. May cause digestive tract irritation with nausea, vomiting, and diarrhea. May cause liver damage. May cause adverse reproductive effects. Warning! Harmful if swallowed. Hygroscopic (absorbs moisture from the air). Causes skin irritation.
Target Organs: Blood, liver, lungs, respiratory system, eyes, skin.
Potential Health Effects
Eye: May cause severe eye irritation.
Skin: Causes skin irritation. Causes redness and pain.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause headache, nausea, fatigue, and dizziness. Inorganic tin salts may cause systemic toxic effects on the central ne rvous system, heart, and liver.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. May cause effects similar to those described for ingestion.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects.
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively. Persons with asthma, chronic respiratory disease, skin disorders, eye problems or allergies may be at increased risk from exposure to this substance.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs
Stannous chloride none listed none listed none listed
OSHA Vacated PELs: Stannous chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - Physical and Chemical Properties
Physical State: Crystals
Appearance: white
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 606 deg C
Freezing/Melting Point:264 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:3.95 (water=1)
Molecular Formula:Cl2Sn
Molecular Weight:189.596
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, dust generation, moisture.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, bromine trifluoride, ethylene oxide, potassium, hydrogen peroxides, sodium, metal nitrates, calcium acetylide, chlorine, moisture, calcium carbide, anhydrous chlorides of iron, tin and aluminum., hydrazine hydrate, organic nitrates, turpentine.
Hazardous Decomposition Products: Hydrogen chloride, irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 7772-99-8: XP8700000
LD50/LC50:
CAS# 7772-99-8:
Oral, mouse: LD50 = 250 mg/kg;
Oral, rabbit: LD50 = 10 gm/kg;
Oral, rat: LD50 = 700 mg/kg;
Carcinogenicity:
CAS# 7772-99-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: Intratesticular, rat: TDLo = 15167 ug/kg (male 1 day(s) pre-mating) Paternal Effects - testes, epididymis, sperm duct.
Neurotoxicity: No information available.
Mutagenicity: Cytogenetic Analysis: Intraperitoneal, mouse = 150 mg/kg.; Cytogenetic Analysis: Hamster, Ovary = 25 mg/L.; Sister Chromatid Exchange: Hamster, Ovary = 25 mg/L.
Other Studies: No information available.
Section 12 - Ecological Information
Ecotoxicity: Water flea Daphnia: EC50 = 19.5; 48 Hr; Unspecified Terrestrial fate: At a low pH, increased uptake of tin occurs as a result of increase solubility. The translocation of tin by plants is reduced by low solubility in soil. The insolubility of tin at a neutral to alkaline pH range prevents plant uptake and subsequent food chain contamination.
Environmental: No information reported.
Physical: No information available.
Other: No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: CORROSIVE SOLIDS, N.O.S. No information available.
Hazard Class: 8
UN Number: UN1759
Packing Group: III
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7772-99-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7772-99-8: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7772-99-8 can be found on the following state right to know lists: New Jersey, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 7772-99-8: 1
Canada - DSL/NDSL
CAS# 7772-99-8 is listed on Canada's DSL List.
Canada - WHMIS
This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
CAS# 7772-99-8 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 7772-99-8: OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 OEL-BELGIUM:TWA 2 mg(
Sn)/m3 OEL-DENMARK:TWA 2 mg(Sn)/m3 OEL-FINLAND:TWA 2 mg(Sn)/m3 OEL-
GERMANY:TWA 2 mg(Sn)/m3 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;
Skin OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 OEL-THE PHILIPPINES:TWA 2 m
g(Sn)/m3 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 OEL-THAILA
ND:TWA 2 mg(Sn)/m3 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/
m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN N
EW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
Section 16 - Additional Information
MSDS Creation Date: 6/24/1999
Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Material Safety Data Sheet
Tin (II) Chloride, Anhydrous, 98%
ACC# 01563 Section 1 - Chemical Product and Company Identification
MSDS Name: Tin (II) Chloride, Anhydrous, 98%
Catalog Numbers: AC196980000, AC196980250, AC196981000, AC196985000
Synonyms: Stannous chloride anhydrous; Tin dichloride; Tin protochloride
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
7772-99-8 Stannous chloride 98 231-868-0
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: white crystals. May cause severe eye irritation and possible injury. Causes severe respiratory tract irritation. May cause digestive tract irritation with nausea, vomiting, and diarrhea. May cause liver damage. May cause adverse reproductive effects. Warning! Harmful if swallowed. Hygroscopic (absorbs moisture from the air). Causes skin irritation.
Target Organs: Blood, liver, lungs, respiratory system, eyes, skin.
Potential Health Effects
Eye: May cause severe eye irritation.
Skin: Causes skin irritation. Causes redness and pain.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause headache, nausea, fatigue, and dizziness. Inorganic tin salts may cause systemic toxic effects on the central ne rvous system, heart, and liver.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. May cause effects similar to those described for ingestion.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects.
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively. Persons with asthma, chronic respiratory disease, skin disorders, eye problems or allergies may be at increased risk from exposure to this substance.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs
Stannous chloride none listed none listed none listed
OSHA Vacated PELs: Stannous chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - Physical and Chemical Properties
Physical State: Crystals
Appearance: white
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 606 deg C
Freezing/Melting Point:264 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:3.95 (water=1)
Molecular Formula:Cl2Sn
Molecular Weight:189.596
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, dust generation, moisture.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, bromine trifluoride, ethylene oxide, potassium, hydrogen peroxides, sodium, metal nitrates, calcium acetylide, chlorine, moisture, calcium carbide, anhydrous chlorides of iron, tin and aluminum., hydrazine hydrate, organic nitrates, turpentine.
Hazardous Decomposition Products: Hydrogen chloride, irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 7772-99-8: XP8700000
LD50/LC50:
CAS# 7772-99-8:
Oral, mouse: LD50 = 250 mg/kg;
Oral, rabbit: LD50 = 10 gm/kg;
Oral, rat: LD50 = 700 mg/kg;
Carcinogenicity:
CAS# 7772-99-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: Intratesticular, rat: TDLo = 15167 ug/kg (male 1 day(s) pre-mating) Paternal Effects - testes, epididymis, sperm duct.
Neurotoxicity: No information available.
Mutagenicity: Cytogenetic Analysis: Intraperitoneal, mouse = 150 mg/kg.; Cytogenetic Analysis: Hamster, Ovary = 25 mg/L.; Sister Chromatid Exchange: Hamster, Ovary = 25 mg/L.
Other Studies: No information available.
Section 12 - Ecological Information
Ecotoxicity: Water flea Daphnia: EC50 = 19.5; 48 Hr; Unspecified Terrestrial fate: At a low pH, increased uptake of tin occurs as a result of increase solubility. The translocation of tin by plants is reduced by low solubility in soil. The insolubility of tin at a neutral to alkaline pH range prevents plant uptake and subsequent food chain contamination.
Environmental: No information reported.
Physical: No information available.
Other: No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: CORROSIVE SOLIDS, N.O.S. No information available.
Hazard Class: 8
UN Number: UN1759
Packing Group: III
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7772-99-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7772-99-8: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7772-99-8 can be found on the following state right to know lists: New Jersey, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 7772-99-8: 1
Canada - DSL/NDSL
CAS# 7772-99-8 is listed on Canada's DSL List.
Canada - WHMIS
This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
CAS# 7772-99-8 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 7772-99-8: OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 OEL-BELGIUM:TWA 2 mg(
Sn)/m3 OEL-DENMARK:TWA 2 mg(Sn)/m3 OEL-FINLAND:TWA 2 mg(Sn)/m3 OEL-
GERMANY:TWA 2 mg(Sn)/m3 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;
Skin OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 OEL-THE PHILIPPINES:TWA 2 m
g(Sn)/m3 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 OEL-THAILA
ND:TWA 2 mg(Sn)/m3 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/
m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN N
EW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
Section 16 - Additional Information
MSDS Creation Date: 6/24/1999
Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
