Preparation of Tetramine dichloro palladium Pd(NH3)4Cl2

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LProcess
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Country of Origin: Italy

Preparation of Tetramine dichloro palladium Pd(NH3)4Cl2

Postby LProcess » April 16th, 2018, 11:39 am

Hi there,

In these days I'm interesting to prepare tetramine dicloro palladium, but this salt is highly soluble in ammonia and water.

the process maybe is this:

Pd + HNO3 --> PdNO3

PdNO3 + NH3OH ---> Pd[(NH3)4]+

Pd[(NH3)4]+ + HCl --> Pd[(NH3)4]Cl2

but this salt is soluble and i can't evaporate all the solution, How I can precipitate this salt?

thank you!


Lino1406
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Re: Preparation of Tetramine dichloro palladium Pd(NH3)4Cl2

Postby Lino1406 » April 16th, 2018, 1:56 pm

Ammoniak with nitric acid is explosion risk

LProcess
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Country of Origin: Italy

Re: Preparation of Tetramine dichloro palladium Pd(NH3)4Cl2

Postby LProcess » April 17th, 2018, 12:14 pm

Thanks Lino!

Any ideas are welcome!!


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