You will want to test the gold before buying, as stated above not all tests would involve chemicals, but chemical tests, or a fire assay may be the most important, for these tests you would need chemicals like nitric and HCl (or at least forms of them), if you could not get these in Africa, then you most likely can get what you need to make them or an alternative, HCl can be made from common salt NaCl and sulfuric acid found in car batteries, nitric acid can be made from a nitrate source like fertilizer KNO3 or NaNO3, nitrates can also be leach from soil or even from bat dung, nitrates and sulfuric acid can form nitric acid.
Their are other things you could use to test for gold, a small fusion of the material in a surplus mix of one part ammonium chloride and 2 1/2 parts ammonium nitrate, this fusion will dissolve gold into the heated salts, this fused salts can then be dissolved in a few drops of HCl, and then wetting a Q tip with the liquid, and dropping a drop of stannous chloride would prove gold that there was in the material, it will not tell you how much gold, just that it was present.
But if I was buying or I would not rely on any of these tests above, although they could work to tell me it was gold.
Buying ore would be different from buying a few karat gold rings.
The ore may come in powder or very small flakes or nuggets; this would make it hard to test each piece chemically.
To do this I think you would be best to set up a lab, or find a lab you can trust, melt the gold to bars, drill the bar in several places, and assay the filings either by a fire assay or chemical assay, to do this yourself it would take a lot of study and work to gain the experience needed, I assume in Africa where they deal with that much gold their are assay offices where you could take, or send the fillings to be assayed.