Beirdo
Well-known member
OK, first off, I am quite aware that there is only a minuscule amount of Pt to be found in the very thin layer on hard drive platters... However, dead hard drives are nearly free to me much of the time, and I like a little experiment. Sooo...
Knowing that the base metal is Al, I can see two equally useful ways of attempting this. Both would start with scoring or sanding portions of the platter to expose the aluminum. Of course, if I do this, I'd be careful to get anything I sand off to be in the reaction container as it would likely be coated as well. After that, I would think the two ways to try would be:
1) Add an aqueous solution of HCl to the reactor, and watch the Aluminum generate AlCl3 and H2 gas (plenty of it). The remaining wee bits of solid would include the pitiful Pt coating.
or
2) Add an aqueous solution of NaOH to the reactor, and watch the Aluminum generate Al(OH)3 and plenty of H2 gas. Again, the remainders would include the wee bit of Pt.
If I were to waste my time trying this, which would be the suggested method, and why? I am comfortable dealing with either lye or muriatic acid (obviously not often together, I can buy much cheaper NaCl at the supermarket, thanks) and am aware of the safety concerns for either method. Any thoughts?
Oh, I guess the same could be done with sulfuric acid... I guess that makes a third wasteful experiment to vote on
Am I overlooking a possible aluminum electrolysis option? Using aluminum foil as cathode and the platter as the anode... with what as an electrolyte? It's been a while since I calculated those electrolysis predictions...
Knowing that the base metal is Al, I can see two equally useful ways of attempting this. Both would start with scoring or sanding portions of the platter to expose the aluminum. Of course, if I do this, I'd be careful to get anything I sand off to be in the reaction container as it would likely be coated as well. After that, I would think the two ways to try would be:
1) Add an aqueous solution of HCl to the reactor, and watch the Aluminum generate AlCl3 and H2 gas (plenty of it). The remaining wee bits of solid would include the pitiful Pt coating.
or
2) Add an aqueous solution of NaOH to the reactor, and watch the Aluminum generate Al(OH)3 and plenty of H2 gas. Again, the remainders would include the wee bit of Pt.
If I were to waste my time trying this, which would be the suggested method, and why? I am comfortable dealing with either lye or muriatic acid (obviously not often together, I can buy much cheaper NaCl at the supermarket, thanks) and am aware of the safety concerns for either method. Any thoughts?
Oh, I guess the same could be done with sulfuric acid... I guess that makes a third wasteful experiment to vote on
Am I overlooking a possible aluminum electrolysis option? Using aluminum foil as cathode and the platter as the anode... with what as an electrolyte? It's been a while since I calculated those electrolysis predictions...