PGM ores tend to be very complex with the values dispersed in a matrix of silicates and Aluminates with Iron oxides and sometimes alloyed with iron or Nickel. The best prep is to grind it to a fine powder. Sometimes it helps to digest the pulp in Sodium peroxide or Sodium Hydroxide to a red heat before you try to digest in AR. Fine particles trapped in the matrix can't be digested until they are exposed for chemical attack.
Extract the residue in dilute HCl and digest in AR.