Refining Using Butyl DiglymePosted

[seawolf]

Post subject: Refining Using Butyl DiglymePosted: April 29th, 2007, 4:49 pm


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Joined: February 24th, 2007, 7:10 pm
Posts: 2916
Location: Sherbrooke, Qc Butyl Diglyme is a good variation of the standard Aqua Regia method. You can achieve a gold purity of 99,99+ with BDG. Also, BDG is reusable.
This tutorial will show you how to refine gold using it.

Material:
-Butyl Diglyme (go there if you plan to buy some: http://goldrefining.110mb.com/phpBB2/viewtopic.php?t=99)
-Separatory Funnel (Very very useful. Take a 2L funnel if possible.)
-Hot plate
-Gold Chloride (dissolved gold)
-Oxalic Acid or other precipitant.
-Standard PPE
-HCl
-Water
-Scale
-Magnetic Stirrer (optional)

Here is the tutorial link:
http://goldrefining.110mb.com/Tutorials/BDG%20refining.htm

Questions or Comments:
http://goldrefining.110mb.com/phpBB2/viewtopic.php?p=5455#5455

[img::]http://i14.tinypic.com/4xzt7kg.jpg[/img]

Very pure gold achieved with BDG.

_________________
Hallmarks are lies.


Last edited by Noxx on June 27th, 2007, 7:50 pm, edited 1 time in total.

Noxx: Would it be possible to restore the links in your post? I would like to see them if possible. I read as much on refining as I can find and this has me curious.
Thanks, Mark

 

[Noxx]

I'm sorry, I don't have a backup of this little tutorial...

Material:
-Butyl Diglyme (go there if you plan to buy some: http://goldrefining.110mb.com/phpBB2/viewtopic.php?t=99)
-Separatory Funnel (Very very useful. Take a 2L funnel if possible.)
-Hot plate
-Gold Chloride (dissolved gold)
-Oxalic Acid or other precipitant.
-Standard PPE
-HCl
-Water
-Scale
-Magnetic Stirrer (optional)

Did I really write that ?

 

[goldsilverpro]

This is the only paper I have on it.

 

[Macgiver]

New to the forum and excited to be a part of it. Thank you in advance.

I LOVE the BDG process and have very consistent results with it. Now, I am working on using it on very pregnant AR solution and I am wondering if I would get better results by evaporating (vacuum distilling) the nitric acid out of the AR before extracting with BDG.

Anyone have any thoughts on this?

Thank you again.

CW

 

[Anders Hoveland]

yet another obscure way to dissolve gold, although the chemicals are not commonly obtainable:
http://pubs.acs.org/cen/news/89/i14/8914notw4.html

a 1:20 ratio SOCl2-dimethylformamide mixture dissolves gold quickly, but it leaves palladium and platinum untouched; a 3:1 SOCl2-pyridine mixture dissolves gold and palladium rapidly, but it leaves platinum alone.

 

[seawolf]

Thanks for posting the link, now I will have a bunch of reading to do then some experiments.
Mark

 

[4metals]

UG Pyridine! one sniff and you never forget the stink!

 

[goldsilverpro]

I used to have to use pyridine in some analytical methods. The lab had a small fume hood, dedicated only to the use of pyridine. It had a small sink built into the back of it. The sink was used to rinse out the glassware before removing it from the hood. Worst smelling stuff on the planet. I remember reading once that the odor actually created clinical depression.

 

[4metals]

I used it to titrate total cyanide in a waste stream, using pyradine-pyrazolone. The cyanide liquor had to be acidified and captured in a sodium hydroxide bubble trap to convert all of the cyanide to sodium cyanide.

I was one happy camper when selective ion probes came on the scene!

I last used the stuff in 1974 and just last year I got a whiff of the stuff in a chem lab slated for a cleanup, still remembered the smell after all of those years!

 

[g_axelsson]

I'm sorry, I don't have a backup of this little tutorial...

Material:
-Butyl Diglyme (go there if you plan to buy some: http://goldrefining.110mb.com/phpBB2/viewtopic.php?t=99)
-Separatory Funnel (Very very useful. Take a 2L funnel if possible.)
-Hot plate
-Gold Chloride (dissolved gold)
-Oxalic Acid or other precipitant.
-Standard PPE
-HCl
-Water
-Scale
-Magnetic Stirrer (optional)

Did I really write that ?

I found a copy on the wayback machine, https://web.archive.org/web/20120511153436/http://goldrefining.110mb.com/Tutorials/BDG%20refining.htm

Here is a pdf printout of the tutorial.
View attachment Gold Recovery Butyl Diglyme.pdf

/Göran