flashfossilized - per the bold print (above quote) you NEED to better understand how these XRF (x-ray spectrometers) actually work &/or how they are programed
Not all XRFs are created equal (programed the same)
XRFs are programed with a library of different elements in the library
The more elements programed into the library the
more expensive the cost of the XRF is
Therefore the people that buy/use XRFs - buy them with a library of elements that best suits the needs of their business
In other words they buy an XRF with a library
limited to the elements need in the library to conduct their daily business
Examples; --------
Jewelers - precious metal buyers & refineries will have an XRF with a library of all the PMs plus
some of more common base metals found in PM alloys but
it won't have all the base metals in the library --- there is no need for them to pay the extra cost for a complete library because they are only looking for the PMs & the more common base metals - so their XRF don't need a library of all elements
Scrap yards deal mostly with base metal alloys but not with PMs (Precious Metals) so they buy an XRF with a good BM (Base Metal) library but no PMs (other then maybe silver) in the library
Mining companies that work with ores (rocks) will have the most complete libraries because they are looking for both PMs & BMs as will as non metal elements such a silica
So XRFs are sold as -----------
1) XRF programed primarily for PM readings & limited BM readings
2) XRF programed primarily for BM readings & limited PM readings
3) XRF programed for Geo-Chemical to read both PMs & BMs as well as non metal elements
Therefore - if you shoot something (like a rock) with an XRF that has a limited library in the programing - & the XRF sees something in what you shoot
that is not in the library - it will then
guess at what it is & then tell you it is something that is in the library --- in other words it will lie to you
Here are two examples of my personal experience with XRFs
When I first started refining I took my first gold button into a scrap yard that had an XRF - it was a BM XRF so when they shot the gold button it called the gold tungsten --- that is because the library did not have gold in the program but it did have tungsten - so it guessed it was tungsten & therefore lied about what it was seeing
Then a few years ago some of use got together over in England - Jon had a PM XRF - Goran brought a piece of arsenic ore with him - we shot the ore with Jon's XRF - because arsenic was not in the library & therefore did not recognize the arsenic it guessed at what it was seeing & called it iridium
You can read about that here ---------
https://goldrefiningforum.com/threads/false-iridium-finds.28009/#post-295508
So --- more then likely - the Jeweler you are taking your rocks to has a PM XRF & it more then likely has the same PM programed library that Jon's XRF has --- therefore it likely does not have arsenic in the library - so when it sees the arsenic - but does not recognize it - it
guesses at what it is & calls it iridium
I could be wrong - but I am willing to bet that is the case
The only way to tell for sure is to have an actual PGM assay done on your rocks
In no way would I trust the XRF reading from your Jeweler because he is likely using a PM XRF with a limited library - that does not have arsenic in the library - & therefore is calling arsenic iridium
Kurt