Brown sludge in my silver solution, what is it??

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Ok problem solved.
I have dissolved eveything in the solution that I still have. 600ml of this solution took 43 grams of silver before it was exhausted. I have must added some "3rd nitric leech" there - that is why there was soo much unused acid.
After solution has cooled down I have put the same copper pieces and silver participated without any problems this time :)

Thanks for help :)
 

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