FYI, I found the below which is part of an old post by GSP. Although he was talking about ceramic DIP packages with gold plated caps, the materials used would be the same for a PGA package. The only question is whether a different braze might have been used for attaching non-gold plated caps?
GSP:
“On a sealed package, like that one, about 60%, or maybe more, of the value is in the 2 different gold brazes, neither of which looks much like gold. The 80%Au/20Sn, under the lid, is a pasty dark gray color, especially when heated in air, and the 96Au/4Si braze is a very light yellow color. Don't figure you have all the gold unless the chip is free to slide around. This only occurs after all the gold braze under the chip has been dissolved with aqua regia.”