• Please join our new sister site dedicated to discussion of gold, silver, platinum, copper and palladium bar, coin, jewelry collecting/investing/storing/selling/buying. It would be greatly appreciated if you joined and help add a few new topics for new people to engage in.

    Bullion.Forum

Electrochemistry Electrolysis question

Gold Refining Forum

Help Support Gold Refining Forum:

This site may earn a commission from merchant affiliate links, including eBay, Amazon, and others.

13ishmael

Active member
Joined
Sep 18, 2016
Messages
26
What would happen if one had a pure silver rod or a pure germanium rod for the electrodes in electrolysis. What would occur of the electrolyte was NaCl or if it was sodium thiosulfate?would the electrodes of germanium or silver corrode. Or will they just be deposited in the solution.

I'm trying to refine a gold bar before I sell it.
 
I'm not sure how to answer this. Based on your question I would say you have no clue of how electrolysis works. You need to study more. If you start experimenting you will only create an expensive mess.

Why would you refine a gold bar before selling it? Isn't it already refined?

Göran
 
g_axelsson said:
I'm not sure how to answer this. Based on your question I would say you have no clue of how electrolysis works. You need to study more. If you start experimenting you will only create an expensive mess.

Why would you refine a gold bar before selling it? Isn't it already refined?

Göran
I'm not sure I understand what you mean. Your answer is full of malice, that is not what I need.
Thank you
 
Ishmael--if you look around on this forum, you'll see that very basic questions receive the same sort of reply: "study more." This is not meant to discourage you, it is meant to keep you (and those around you) safe. At the very least, holding off on action until you learn more will keep you from making, as Göran said, "an expensive mess". At best, it'll keep you from seriously harming or killing someone.

Running a gold cell (or just about any electrolytic cell used in refining) involves maintaining a system of heated, concentrated acids.

Also, each type of material tends to have preferred methods (i.e., acid refining for karat gold scrap, cells to further purify cemented silver, etc.). Hence Göran's second question: what sort of gold bars do you have? Where did you get them? What was the source material? If they're mostly pure, perhaps a cell is in order. If it's something else, a cell may or may not be appropriate. There's also a hidden question in there: if your bars are not pure, how do you know there's gold in there at all? Do you have assay results?
 
In any case, I can't see the process working at all, especially with the electrodes and solutions you've chosen. The simplest, fastest, and most efficient way to purify your gold would be the aqua regia process, which is spelled out probably hundreds of times on this forum. This may or may not require inquartation, which is mainly dependent on the silver content of your gold.
 
hello
I have a question about voltage and ampere in gold electrolysis process.how is that ? thanks for your answer
 
Back
Top