Looks like tin plated brass, not silver plate.
There is an easy way to test if something is tin plated. Just rub it against a white paper, if you get a grey streak then it was tin plate. Silver plate is too hard to rub off on paper.
The connectors are just like any connector in electronics. Doesn't matter if it's from a PLC, computer or printer, just look for gold plate and when you find some decide if it is enough to spend your time to get it.
Göran