Thanks Dave, thats exactly the point. (I) Don't use a mask, (I) Use safety glasses and gloves and (I) work systematically to avoid gases and spills to be released. (I) Have neuralizition liquid available for emergencies. (I) Work in a fume hood and close it when possible. (I) Do not start without knowing the risks and how to react if one actually occurs.
I trust my eyes and nose and when I get a small whiff of NOX I first exhale,close the container and move away to a safe area before inhaling. My setup allows for this.
I do all my nitric reactions in a closed erlenmyer flask and bubble the NOX trough H2O2 assisted by a vacuum to scrub most, and actually regain some HNO3. I use a check valve on the inlet to avoid back flow of H2O2 into the reaction flask once it cooles down.
Read the MSDS and act accordingly:
How to protect yourself from say chlorine gas: look up MSDS, read the safety measures.
But knowing when e.g. chlorine gas will come from your reaction, and how to minimize it, will be your first and best protection.
Having the means ready and in place to turn off say energy supply or close off the reaction vessel is step two.
Avoid a runaway reaction (apply only known and tested processes & prodecures, and when experimenting; only with small batches, in over-over-over dimensioned vessles), and you won't have to worry about containing the spill from a boil over.
What I'm saying if you don't trust your reaction, or don't have enough experience or equipment (scrubber vessels/fume hood/beaker cover glass\etc) to make sure it's safe, perhaps not performing the reaction is the safe option.
Personal safety equipment can only be the last measure to bring your risky buisiness within acceptable limits.
Safety is performing a task with a known, calculated risk, and knowing how to protect yourself.
Not diving in with a mask and let's see what happens.
The choice is yours if you are doing the work yourself, its another thing if you are employing! Then you have to protect your workers against the known risks. This level of knowledge must be continuously updated and changes communicated to employees.
Be safe.
Martijn.