Oz said:
Back in the day some 30 years ago at the markets I used to haunt buying and selling they did test with dilute nitric checking the surface of the item as to texture and color both before and after the acid was washed off. Having said that, Schwerter's solution is the way to go.
Just because they did not know better does not mean you need to follow in thier footsteps.
Nitric can serve to make tests to a fairly reliable degree, although I would not recommend one make purchases on the strength of the test results. That applies to gold, of course. Silver can be tested reliably with Schwerters, assuming you have enough experience with the reactions. It's a good idea to test various alloys to become familiar with the color reactions, which turn more towards brown as the silver content diminishes. Some of the Scandinavian countries have silver standards that are much lower than sterling. I processed flatware that was marked 720, or 72% silver.
Fact is, ten karat and lower will react to nitric, leaving the surface a darkened brown color. That's the results of dissolving traces of alloy, leaving behind the partially divided gold. 14 K and above will remain unchanged aside from being well cleaned. I already described the effects nitric has on silver, so, yes, nitric alone can be very telling, especially when you've made countless tests and are able to interpret the results.
The nice thing about Schwerter's is it tells no lies. You need not interpret anything----if you see red, you know you have silver. The only remaining test would be to file a notch in the item and test for base metal (silver plating instead of solid silver). Schwerters will serve for both tests. That's the reason it is included with gold testing kits. You can test for base metals in gold filled and plated items.
I agree-----that others fail to use good and accepted procedures is no reason for others to fail to do so.
Harold