Mattafc,
This will sound harsh, but I am only looking out for you, and you spending your money wisely. In your other posts you are looking for a furnace recommendation as well as crucible recommendations. This leads me to believe you have not even cast precious metals before, and yet you are ready to spend $30,000.00 and up for one piece of testing equipment.
If my written assumptions are correct, have you lost your mind?
I know everyone talks about XRF and ICP like they are top analytical equipment, and they are. Truth be told however, their accuracy is completely (extremely) dependent on your skill in its operation and your level of experience with it.
If you have money to burn, great! If not, learn the basics first.
It may help if we knew whether you were trying to check purity in order to buy (non-destructively), or just checking your purity going out the door after you have refined. If it is the later, there are far less expensive ways to determine the purity of the metals you are refining than XRF.