Hi all!
I am Ivan from Indonesia.
I have raw material containing 5% rhodium.
I would like to try to fusion with NaHSO4 for my raw material for rhodium.(from black sand) but i dont know where to start.
I have passed the roasting 500oC for 4hours, the leaching with HF and then nitric acid, the Hot Aqua regia to dilute Au, Pt, Pd.
and now i get residue which positively contains Rhodium(and might also Os,Ir), rose red colour, using steve method to test rhodium.
I dilute the residue with sulfuric acid for 2-4hours, then adding lots of water before siphoning.
I precipitate the rhodium or everything using Tin. I get black powder.
I have legitimate reports from local metallurgy lab that the raw material contains 5% rhodium. I am not a dreamer but i am just curious. I would like to precipitate pure rhodium.
how to deal with the black powder? or getting pure rhodium from the black powder?
i cant get any NaHSO4 in Indonesia. Is there any substitute chemical? or is it possible to make NaHSO4?
I might sound like any other guy in the forum trying to proof that their material contains rhodium.
I am just curious, the country as big as Indonesia has no PGM's mining except gold mining.
FREEPORT, the biggest gold mining in Indonesia, in Papua, Papua New Guinea Island which i believe, mining PGM's not only gold, chopper, and silver.
please do look at the website www.ptfi.com
Papua is the richest island in Indonesia but the poorest people among others island.
My point is, I email and join the goldrefiining forum for the enlightment.
Papua is the cendrawasih island and Freeport is only small part in papua which contain gold. My papua friends tell me that," If Papua is assumed as a body that contains gold, than Freeport is only hand." They, Freeport, are hunger for more.
Sounds like politician.. but i am just curious and need enlightment.
Thanks