Sure, there is a place for "cherry picking" and finger, chip and CPU small scale recovery, but it is more of a niche opportunity, a side venue of larger e-waste stream.
This is very true. Especially when getting regular shipments in, and is something I do personally. In my instance, most of the material that comes in has to be shredded, however, I do get smaller loads, or am allowed from the source to pull some pieces for my personal stockpile before the rest goes in the shredding equipment. The smaller loads that come in get the best stuff sorted out, and added to the personal stockpile, the rest goes to various board buyers, as I'm not usually required by those sources to shred.
As individual without the help of e-waste collecting facilities, you will need very very large net of "sub-contractors" to fill your crates with good stuff. It requires quite a lot of labor as you say to manually cherrypick the good stuff from big piles of e-waste at some facility. And even more work as you say for preparing the stuff (like trimming fingers, removing chips or BGAs).
This is a very good point made as well. The original poster seems to have the ability to find a potential decent source, so that's a good start.
Based on what you said and what Neiks neims said, some things that I have experienced so far (although I've only had a few experiences trying to buy this stuff) are starting to make sense.
It is very difficult to break into the business, finding your sources are key. You will have to fight for it, because a lot of businesses, including mine already have them as a contact, and have the equipment/facility/etc.. What you should focus on is making contacts, and partnerships. I would locate people near you that have the equipment to handle the end process, and the licenses, then I would go out and look for odd sources that are outside the box. The best sources are larger facilities like warehouses, offices, or store fronts with high turnover rates of their product. Another route you could take, is say, find someone with the shredding equipment, and work out a deal to be a collection point for that business. You would need a dedicated space for a bin to be placed, the bin could be the size of a 10 yard dumpster. If you're residential, you may need to make that dedicated area the garage, as to not be unsightly. You will have specifics in place of what you take in, how take them in, what you have to reject, and so on and so on. Once you're able to display you can do this for a company that has the equipment, and partner up, they can usually extend their license in some aspects to you, as technically you would be working for them.
If you end up doing this, you would most likely only take in laptops, desktops, occasional server/networking equipment, routers, dvrs, cable boxes. Only as a collection point though, no money exchange, not buying it from people, and unless you work it out with the business you're partnered with, you're not allowed to keep any of the equipment brought in. It's gets very technical, and is advisable to have a thorough daily record of what is brought in, and recorded camera coverage to be able to show the business. Things you would not take are tvs, monitors, printers, batteries, anything with chemicals, or capable of causing harm if improperly stored for almost any reason.
One other route you could take, is get a resale license, and only advertise as buying used equipment, you will have to still have a place that you're able to prove that you took equipment to for proper disposal if you do anything beyond selling the equipment as it is. the places could be various board buying facilities or operations like mine, but the places must have the licenses to do it.
Just food for thought.