I have seen it used with salt to clean placer gold and in treating black sands to reveil tiny gold partcles stuck to the sand or encapsilated by the sand.
vinigar contains 5%-18% acetic acid, a weak acid, attacks Iron, Zink, Magnesium, it also has been mixed 50/50 with nitric acid for nickel. it can also disolve sulfur and iodine.