modtheworld44 said:
Traveller11 said:
By the way, the soluble gold product created with this leach is not the usual gold (III) chloride or auric chloride (formula AuCl3 or Au2Cl6) that is made with the Acid/Clorox process. This leach will produce something called sodium tetrachloroaurate or sodium gold chloride for short, with a chemical formula of NaAuCl4. From what I can gather, the precipitants used to recover metallic gold from auric chloride will work on this, as well.
Traveller11
Does this leach base metals as well or does it work similar to the way cyanide leaches gold?
modtheworld44
Unfortunately, it will leach base metals, as well, as chlorine is very reactive. However, because it is not an acidic leach, but rather is close to neutral in pH, it cannot break the bonds of metal oxides (ie. haematite and magnetite). This is why, in the 1890's, ground ore was roasted, in the presence of oxygen, prior to leaching with this method. Roasting broke up the pyrites, turning the sulphur into sulphur dioxide and the iron into an oxide of iron. Any free iron in the ore was also turned into oxides. Large amounts of copper are also poison on this leach, unless oxidized as well.
Another drawback to this leach is that the process must take place inside an airtight revolving container, with either ALL of the air excluded by completely filling the container with ore and liquid, or by pumping air into the container and maintaining a pressure of 60 psi. In the 1890's, this pressure was created by mixing two chemicals together inside the sealed container to create chlorine gas, which then dissolved in the water in the container. Chlorine gas which did not dissolve built up pressure inside the container, achieving the same purpose as pumping in 60 psi air. This container must be either plastic or, if made from steel or other metals, plastic or lead lined to prevent the chlorine from reacting with the metal. Even stainless steel will react with chlorine and, outside of lead, the only other suitable metal is titanium.
The reason for excluding air, or for raising the pressure, is that hypochlorous acid (HOCl), the lower pH alter ego of sodium hypochlorite (NaClO) bleach, is, unlike sodium hypochlorite, a very powerful oxidizer and, for that reason, is very unstable. It wants nothing more than to lose that lone oxygen atom to the atmosphere and go from HOCl to HCl which is, of course, hydrochloric acid or hydrogen chloride. In the water system I operate, this can easily be proven. I add sodium hypochlorite bleach to drinking water, as a disinfectant, by means of a metering pump and injection nozzle. As the pH of our water is typically 7.5, this hypochlorite gets converted to a roughly 50/50 mixture of sodium hypochlorite and hypochlorous acid. I measure this mixture out in the system on a regular basis as "free chlorine" by means of a reagent. Once all the reactions with bacteria, organics and metals such as iron and manganese have occurred, the remaining free chlorine will stay in the water for as long as two weeks, temperature dependent, before the free chlorine is depleted. This is because the water pressure in our pipelines is a static 94 psi. However, once this water is poured from the tap into a glass and left to stand at atmospheric pressure, the oxygen atom is quickly lost from the HOCl and, within half an hour, most of the free chlorine is gone from the water. The same will happen with this leach. If attempted in open air, the oxygen will take the path of least resistance, and instead of oxidizing gold, will be lost to the atmosphere. The resulting HCl will also begin lowering the overall pH of the solution, and, once under pH 5, chlorine gas will be released. At a lower pH, the increased acidity is also enough to break the bonds of the metal oxides, putting base metals into solution and not gold.
Strangely enough, I thought the sole purpose of revolving the container was to keep the leach and ore mixed and in contact with each other. From reading an old mining paper, I learned the other purpose was to keep the gold particles in motion in order to abrade the silver chloride precipitating on the gold particles. It seems that silver chloride will form an impenetrable coating on the gold particles and impair the leach process. Constant tumbling knocks the silver chloride off, as, from what I have read, it does not have a strong bond to the surface of the gold particle.