I am assuming your talking about testing metal (not for testing metals in solution which would use different reagents).
Search for pawnbrokers guide to metals testing, and also Hoke's book on testing precious metals.
You can make your own solutions of gold testing acids with HCl and HNO3, these range from pure nitric to dilute and concentrated aqua regia, note aqua regia testing solutions have a shelf life.
Potassium dichromate can be bought to make schwerter's solution for testing silver (and other metals), or you can just by the solution.