Dissolve PALLADIUM CARBONATE with HCL

[joandinan]

Hi i'm from INDONESIA.

can PALLADIUM CARBONATE dissolve with HCL, and precipitated as (NH4) 2 (PdCl6) ...?

if reading the article from google patent that i include,
I assume if palladium, silver and other base metals are dissolved with HNO3, to obtain palladium can be done with a little trick without the need for DMG or other. can anyone comment on this ...?

(sorry if my English is bad)

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[Lino1406]

Ammonium hexachloropalladate for achieving what?

 

[joandinan]

Ammonium hexachloropalladate for achieving what?

thank you Lino. sorry I late for reply.
I have 1kg metal alloy, copper, silver, lead and palladium. I will dissolve the metal alloy with nitrate, I plan to recover the silver and palladium by adding a sodium carbonate on the solution of nitrate to pH 8 - 10, after sediment / suspension, I plan to recover the silver by dissolving silver, palladium .etc with HCL and silver will be a silver chloride
and palladium .etc will soluble by HCL. from this step, can i increase the value of Valence palladium to palladium IV and precipitate palladium as NH4Pd2Cl6 ... ???

thank you previous Lino

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[Lino1406]

What you need Ammonium hexachloropalladate for?

 

[joandinan]

What you need Ammonium hexachloropalladate for?

because I'm only able to recover palladium that way. I do not know any other way, like from a nitrate solution, I can only recover palladium with selective chloride solution. I'm not an expert [WHITE SMILING FACE]

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[joandinan]

What you need Ammonium hexachloropalladate for?

any suggestion for me ..? I usually add zinc to the nitrate solution, and purify the palladium by dissolving it with aqua regia. And next time I want to try with other methods.

I hope there is a cheap way of recovering palladium in nitrate solution and how do you think with NaOH and FORMALDEHYDE ?

Thanks Lino


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[Lino1406]

Better to act with A/P this will leave palladium as is, copper in solution, PbCl2 and AgCl as white sediments

 

[joandinan]

Better to act with A/P this will leave palladium as is, copper in solution, PbCl2 and AgCl as white sediments

Oh ...., thanks God.

And thanks Lino, I almost forgot this Methode, simple and inexpensive,
......until you told me.

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[Platdigger]

How can you say A/P will leave pd as is? I have put pt into solute with this.

 

[g_axelsson]

I thought CuCl₂ by it self could dissolve palladium.
It's part of the Wacker process, but maybe it requires heat or pressure to work. I've never tested it other than I have some copper chloride solution that tests positive to palladium.

Pd + 2CuCl2 → 2CuCl + PdCl2

https://en.wikipedia.org/wiki/Wacker_process

Göran

 

[Lino1406]

This could be a long (several days) procedure, followed with testing of dissolved Pd until the optimal concentrations decided. In the worst case, some Pd will dissolve with Cu.

 

[joandinan]

This could be a long (several days) procedure, followed with testing of dissolved Pd until the optimal concentrations decided. In the worst case, some Pd will dissolve with Cu.

thanks. I'll try your suggestion.

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[joandinan]

I thought CuCl₂ by it self could dissolve palladium.
It's part of the Wacker process, but maybe it requires heat or pressure to work. I've never tested it other than I have some copper chloride solution that tests positive to palladium.

Pd + 2CuCl2 → 2CuCl + PdCl2

https://en.wikipedia.org/wiki/Wacker_process

Göran

Thanks Göran.

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