jason_recliner
Well-known member
I'm not actually sure whether you're being serious or joking. I wouldn't like the stuff to contact my skin at all. I generally wear nitrile gloves until I am working with water. Though I admit to the odd bit of handling without. AP will take off skin pretty darned quick.lysdexic said:I'm just checking I don't need gloves right? Copper chloride solution can't be good for your hands or any other part of your body. If I were that stupid with some of the other processes ...well we know what could happen.
Yes. Yes. No. Yes. Yes.I'm a little confused and I don't mean to sound like someone who knows what they are doing because I'm not. I'm just barely to the point where I just might be able to pursue being a beginner, not even an apprentice. You're processing waste acid with copper to cement values there's SMB and possibly Nitrates along with a black powder precipitate? Is this left over poor man's nitric (edit... I meant poor man's AR) that you dissolved gold in? Was it tested? Did any gold drop? Does free sodium nitrate mean there's still nitric acid that should be neutralized before gold can be dropped? I haven't really looked into the process because I don't plan on using it. I purchased 5 gal. of battery fluid (35%? {would have to go look} sulfuric acid) and intend to concentrate it to 98% and use Steve's formula for cold nitric which I plan to distill afterwards. That's still beyond my currant capabilities, so it'll be a while.
I didn't have stannous at the time, but copious SMB dropped my brown powder. Then a possum dropped my brown powder. I assumed the waste was now gold free, but after some wash-diluting, black stuff dropped a week later. Probably some nitrate evaporated? Reading here made me realise there might be more gold, I added copper. No more powder, yet, but I have enough acid in my jar to slowly get rid of a sensibly priced car.
Adding sodium nitrate (made from ammonium nitrate, thank you Nurdrage - I might be able to cut out the middle man in future??) to HCl will make a weak salty nitric. There's still probably enough nitrate to not drop any more gold despite the masses of SMB, and there's certainly enough of either to confuse my stannous tests. Even my nice, cleanest (SMB still free) "yellow stuff" makes for a purpley-brown test. I'm not touching it until I get the nitrate out. It's just sitting under a clear seedling cover on the front deck in the sun for now. I hope sunlight doesn't screw with it. My "light green stuff", which I know has gold "with a hint of copper", because I put some in and didn't take any out, does not give a stannous result. Probably because of the nitrate.