anachronism said:To be very honest using cyanide is all about common sense. Work in a vented area, make sure your pH levels are correct, don't eat, drink , or smoke, and use the proper protocols for handling the liquids. Have a spill procedure in place too.
It's not the demon that people have suggested that it is provided you have common sense and a good set of safety procedures. That given, if you're already unsafe using other chemicals because of your slipshod methods then don't go near this stuff. The key difference is simple: Get it badly wrong with this and you don't get a second chance. Get it right and don't get over confident and it's a dream to work with.
Read up on the definitions of ppm, and free cyanide and how free cyanide is made up both CN- ions in solution and HCN in solution and how the percentages vary with pH. The short version is that at pH 11+ your free cyanide is 90 plus percent in the ionic form rather than the dissolved HCN gas. Hence why the "manuals" recommend this as a minimum pH.
In summary if you're a newbie or you consistently fail to grasp lab safety protocols then steer away from this like the plague. If you don't even understand the chemistry behind it then wait until you do before trying it.
Jon
Thanks Jon...most of my readings have determined exactly what you just said. There's still something comforting about the meter though. Maybe I should just get a canary. Right now, I'm looking at having a small shed/building that is dedicated strictly to cyanide. That way the hood can be set up for the free cyanide titrations, and kept set up. I can also set up a small electrowinning cell in the hood, and just leave it set up.
Do you have your system up and running yet?