I run an XRF for assay purpose. Originally it was bought to replace acid or at least make the process of identification at the counter with the client faster and accurate. It did neither.
#1 you need to tell IT what purity your sample is (sort of defeats the purpose)
#2 it won't penetrate the sample beyond the surface (or maybe a few microns) so gold filled, slver plated... those samples will appear as if they are solid material (terrific for those less experienced or caring buyers)
#3 if you get the PC detector... it won't measure much below 50% purity
#4 if you get Si-PIN detector you will spend $20k+ range but it is much more accurate vs. the PC detector (big bucks)
#5 it works will when YOU know the sample so if you need to get near exact measurement of gu, gd, cu, pt, pd and so on. But unless you assay... why do you need this? (if you are using to buy from the public - this is not necessary)
I sell these machines, by the way, and I talk more of my stores out of them because I refuse to sell them something they don't really need. Instead.. buy a specific gravity scale! We use ours 100x a day and it is super easy and quick for under $1k. Coins, bars, nugget, jewelry... you name it. The on-board computer tells you everything and has little downside (won't work with hollow sample or smaple with stones). I sell these too by-the-way! I'd say get this first and if you think you need assay machine - get the Si-PIN detector and drop $19k on one of our Skyray units. I'd still try and talk you out of it.