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Non-Chemical Gold tarnish problem

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mr-fixit

Member
Joined
Sep 19, 2011
Messages
15
I've Been making 1g globules of gold from a 24 carat bar. I cut 1g from the bar then melt it with a butane torch on a stainless steel plate. The problem is some of the globules are discoloured on top where the flame hits the metal, but the under side remains ok. Why is this and how do I rectify it?
 
In addition to the above post.

If I turn the globule over so that the tarnished side faces down and the normal side faces up then re-melt, the tarnished side goes back to the top where the flame is and the underside is normal. There must be a simple answer.
 
You've contaminated the gold with iron, etc., from the stainless. Gold alloys readily with iron. The discoloration on the top surface is oxidation of part of those contaminating metals. The top surface is exposed to the air and/or oxygen from the torch. If you used a reducing flame, you might not see the contamination but it would still be there.
 
mr-fixit said:
What type of melting platform does not contaminate PM,s

Fireclay, clay/graphite, silicon carbide crucibles. Any of the jeweler's melting dishes. Soft firebrick that has had an indentation scooped out with a spoon. NO metal!
 
TXWolfie said:
Ok will he have to add borax and use a crucible for this or am I wrong

As goldsilverpro stated the gold was contaminated by something not gold. From reading many posts on this forum you will probably need too drop it in acid to pull the gold, then drop it out of the solution, remelt in a clay crucible. My previous statement, please excuse what I typed. I was in the middle of a conversation and what my fingers typed was not being said in my brain to type (brainfart). There is alot of posts on how-to's you just have to find one and go step by step. Since I am fairly new to this and reading alot and watching video's this is what I would believe is needed to be done, but there could be an easier way. Hang in there and there might be an answer from a more knowlegeable person. Just trying to help out on the forums.

Rich
 
So its possible to decontaminate my gold. Could someone put me in the right direction, bearing in mind I am new to this.
 
http://goldrefiningforum.com/phpBB3/viewtopic.php?f=61&t=5204&p=44752&hilit=contaminated+gold+borax#p44752
 
exactly, dissolve the contaminated gold and re-refine it if you are concerned with purity. borax in addition to a form of lubricant for you crucible/melting dish is also for removing surface impurities that may occur from a dirty torch tip or carbon from the fuel like acetylene will cause.
 
woohoo I answered it correctly, I feel so proud of myself. I would pat myself on the back but to busy typing. :lol:
 
This may be very silly.
Could I clean the surface with sulfuric acid, re-melt clean etc until the cotamination has gone?
 
sorry. the discoloration you see is just the reaction of oxygen on the surface of the metal. the contamination is all the way through the piece. melted gold will alloy with almost any metal and acts like a solvent so when the melted gold touched the steel it pulled the steel into the matrix.
 
Geo said:
sorry. the discoloration you see is just the reaction of oxygen on the surface of the metal. the contamination is all the way through the piece. melted gold will alloy with almost any metal and acts like a solvent so when the melted gold touched the steel it pulled the steel into the matrix.
Wow I guess I am learning I was gonna say the same exact thing.
 
Er............em
I started with 1g of 24k and the end result is a 1g button. So its purity must be high, 23.99k ? If so whats ethicly wrong with cleaning the outside?
 
Cause if it is thru-out it will still come to the surface part of the gold that is touching the air.
 
Yes Jimdoc he is cutting 1g from a bar and melting it on stainless steel.


mr-fixit said:
So if I clean it it will re-tarnish in time?

Yes as long as the gold was melted on anything metal it will always have that metal in the Au. The gold acts like a sponge and pulls it in to the mix. Like said before ya wanna get rid of it ya have to reprocess it and melt it on Fireclay, clay/graphite, silicon graphite crucibles. Any of the jeweler's melting dishes. Soft firebrick that has had an indentation scooped out with a spoon. NO metal!
 

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