Generally a high voltage contact is of a tungsten alloy. If you happen to have a melting furnace or forge toss it in. Tungsten won't melt however hot your home forge may get.
I don't mean to be rude here but this is a somewhat misleading post
First of all - just because they (contacts) are high voltage does not mean they will be tungsten (alloy)
It is not a question of their voltage that determines if they are made with tungsten - or other alloy
Rather - it is their "application" that determines what they are made of
Secondly - IF (the BIG IF) they are made with tungsten then they will be a "sintered" product & NOT a true alloy
An alloy is made where two or more metals are actually "melted" together making an actually "chemical bonding" of the metals with each other in "the alloy"
A sintered product is made by taking two or more metal "powders" & "compressing" them under HIGH heat & HIGH pressure so they are NOT actually chemically bonded - they are just different metals packed "very tightly" together
Generally speaking - about the
"only" place you will find the "sintered" tungsten/silver type contacts is in hand thrown circuit breakers" --- such as the circuit breakers in your house hold electrical panel as well as LARGER industrial "hand thrown" circuit breakers --- these points run between 60 - 70 tungsten & 30 - 40 percent silver
These points can NOT be melted in a furnace due to the VERY high melt point of the tungsten (which why they are sintered & not a true alloy) nor can they be simply dissolved in nitric like you normally dissolve silver "alloys" --- in order to leach the silver "out" of the sintered tungsten they MUST be literally BOILED in nitric & to get ALL of the silver leached out of the tungsten it can take 24 hours to 48 hours of BOILING them in nitric
The other more/most common types of contacts are ether high voltage "magnetic disconnects" - or low voltage relays
High voltage magnetic disconnects will ALWAYS be a silver "alloy" & will generally be "about" 90% (plus) silver - these will melt in a furnace & as well dissolve in nitric like any other silver (true alloy)
Low voltage relays can be a silver alloy - or gold "plated" silver - or silver/palladium alloy - or solid palladium - or silver & other PGM alloy - or other solid PGM
There are a FEW other types of silver contacts /switches out there but they are not real common
This is why I asked for pics of what the OP has - so we can determine the "type" switch/contact he has & then determine if (worth) &/or how to process
Kurt