leavemealone said:
Harold I know the video that he is reffering to.I don't think he explained enough to recieve an adequit response(no offense scrapit).In the video a company melts all of the base metals,precious metals,and pgms together,pour it into a thin plateand use it as an anode in a cell.Then using various cathodes they extract off the metals starting with copper using a copper cathode,then silver using a steel cathode,and finally a high percentage of gold is left as the anode.It is most certainly not pheasable for the scale of recovery and refining that we do.In the same time it takes me to melt a couple of pounds in my foundry,the larger smelters can melt tons.
Thanks for the input. There are a couple interesting points you divulged, although I'm still not convinced that the process works as suggested. For one, cathode type makes no difference as far as which element is recovered. Electrolyte, and possibly, voltage, does.
Assuming the plates are thin enough, and the balance of combined elements is reasonable, I can see how you could extract them with some degree of success. The process would be akin to inquartation, leaving behind a honeycomb of material once the first element was recovered. Extracting from both faces, with a thin anode, may allow total extraction before the alloy was isolated. Dunno.
The basic concept is akin to that which is used by the "big boys" in that they cast bars high in copper and part them in a copper cell, or so we're told. I would not be surprised to discover that the bars are fed to a large reverberatory furnace, where base metals are eliminated in the slag, or exhaust (zinc). Copper refineries must keep their electrolyte in balance in order to achieve the desired results, so they avoid carrying base metals with the copper.
I have personal experience with parting copper that is not of high purity. It's not as simple as it sounds, and doesn't work as would be hoped.
Where you been? Haven't seen you here for quite some time.
Harold