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Silver cell electrolyte

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Joined
Oct 12, 2024
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Location
Havana Arkansas
Hi all. I have a question regarding the life of the electrolyte in my silver cell. I have 135g/liter electrolyte and I've ran 50 ozt through it the second time and the electrolyte is still crystal clear. Is there a limit to how much silver it will dissolve before being depleted? I know it turns blue when it gets copper in solution. Just curious as to how long it will hold up. To reiterate, it's the second time through the silver cell. Thanks

Tony
 
The answer to your question is it depends on what type of materials you run, the biggest problem with cells is the fouling of the electrolyte causing co depositing of other metals.
 
If your feed material is high purity Silver >99%, a cell will last a long time because the nitrate is regenerated at the cathode when Silver is deposited and it picks up another Silver ion from the anode. Only when base metals build up in the electrolyte, typically indicated by color of the solution, does the electrolyte get depleted because the base metals consume the nitric and leave less nitric to digest Silver at the anode. Back in the day of cheap nitric, cells were run with cemented Silver which had high purity and the cells ran long and produced a lot of Silver with little maintenance. Today running sterling through a cell requires adding extra nitric to keep the Silver content of the electrolyte up because the copper requires over 3 times the nitric as Silver to dissolve. So the nitric drops, the copper concentration increases to a point where the Copper is high enough in concentration to co deposit at the cathode and produce impure Silver.
 
Hi all. I have a question regarding the life of the electrolyte in my silver cell. I have 135g/liter electrolyte and I've ran 50 ozt through it the second time and the electrolyte is still crystal clear. Is there a limit to how much silver it will dissolve before being depleted? I know it turns blue when it gets copper in solution. Just curious as to how long it will hold up. To reiterate, it's the second time through the silver cell. Thanks

Tony
If you read this thread, you'll learn that you can clean up the copper nitrate from your electrolyte with a graphite cathode.
Fine details are in the thread.
Thread 'Processing Sterling Silver without nitric acid' https://goldrefiningforum.com/threads/processing-sterling-silver-without-nitric-acid.2868/
 
If your feed material is high purity Silver >99%, a cell will last a long time because the nitrate is regenerated at the cathode when Silver is deposited and it picks up another Silver ion from the anode. Only when base metals build up in the electrolyte, typically indicated by color of the solution, does the electrolyte get depleted because the base metals consume the nitric and leave less nitric to digest Silver at the anode. Back in the day of cheap nitric, cells were run with cemented Silver which had high purity and the cells ran long and produced a lot of Silver with little maintenance. Today running sterling through a cell requires adding extra nitric to keep the Silver content of the electrolyte up because the copper requires over 3 times the nitric as Silver to dissolve. So the nitric drops, the copper concentration increases to a point where the Copper is high enough in concentration to co deposit at the cathode and produce impure Silver.
Thank you! I am feeding it high purity silver that's been through the silver cell once already.
 
Thank you! I am feeding it high purity silver that's been through the silver cell once already.
If this is the case it explains why your electrolyte remains clear and your cell will enjoy a long productive life with the nitrate ion picking up and dropping off Silver from the anode to the cathode and no nitric is consumed in the process.
 
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