What are the ways to determine Silver has purity of .999?

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w0lvez

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How can you determine if silver is really pure?

Excluding gold and copper, Is it possible to alloy or filled silver to other metal like Tin or Nickel?
 
You can weigh out a sample (precisely) digest it to make silver nitrate, and titrate it with N/10 potassium thiocyanate. Very accurate and quick.

GSP covers the topic completely in his e-book, worth the money for the silver chapter alone.
 

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