justinhcase said:
Has any one run the comparative cost's on each method.
I still proffer a good rotary evaporator to trying short cut's.
Sulfamic is handy for small quantity's and so you only need to reduce down once as I do.
Solvent extraction is good also and help's with high purity refinement.
"Versenol 120" made by Dow chemical looks very interesting as it is meant to let you drop form a solution with 50% nitric acid .but it is a bit pricey.Has any one tried it and compared cost's?
Cost's are not an issue at the moment,but when you look at scaling up even a slight saving could mean the difference between having a stable business and going hungry.
But it is the simplicity of evaporation I am drawn to and the reduction of low solubility impurity's is a bonus,apart form specialist precipitant's the other solution's add complication to the process and require intensive work,where as a batch evaporating can just be left to reduce down by it's self while you get on with other work so increases productivity.
Justin - sorry for the delay in responding but I have been "very" bussy
I don't think it is so much a question of cost of one method over that of another - rather it is more like Jerry pointed out (speaking of "his" process)
The variations of this process that I choose to use gives me several options to use depending on what type materials I run through it. It all comes down to process preference in the end for me and the speed in which it allows me to turn over my gold
In other words it really comes down to what you have going on in your particular situation - things like are you processing your own material or someone else's - how much material are you processing - is it material you get on a regular bases or only from time to time & are the lots you get to process large or small - etc.
Examples -------
This batch of GP 0n SS was a
one time small batch - am I going to go buy a product like Versenol 120 to drop my gold in such a case - no - on the other hand if I was getting this material in on a regular bases & in large quantity's I would most certainly look into that as "an option" --- this option might cost more money wise - but on large & regular material for a customer it would pay for its self time wise & allow for timely return payment to the customer
You mention using a rotovap & that is certainly an option with the benefit of being able to recover your nitric for reuse - the down side is it would take forever if you were working on large batches on a regular bases for a customer - so its not practical for getting the job done to make a timely return payment to the customer - Versenol 120 would be the better option
If its your own material (GP on SS) & you have a lot of GP pins to process then using the pins to cement the gold makes sense because you kill two birds with one stone --- you recover the gold from the reverse AR as well as recover the foils from the pins
If its a small batch one time thing & you don't have copper for cementing sulfamic might be the answer
I choose copper cementing because (1) it was a small batch (2) I have LOTS of copper (& it only took about $3 worth) & (3) it only took about an hour to "recover" the gold to then go for refining --- so it was cheap - & fast allowing to make timely return to the customer --- & as I explained here :arrow: http://goldrefiningforum.com/phpBB3/viewtopic.php?f=61&t=22916&start=30#p240874 --- I still have free nitric which I will "finish" using up to recover foils from pins or fingers
Or as I explained here :arrow: http://goldrefiningforum.com/phpBB3/viewtopic.php?f=61&t=22916#p240544 --- cementing just makes good sense
The point being that what you have/get &/or who it belongs to &/or how it fits into your processing circuit all play a greater roll in deciding method options then the cost of one method over another
Kurt