The AP process is excellent at dealing with copper. If you were processing only fingers, where copper is the main base metal being dissolved, it can be regenerated over and over. Pins are very different. They're almost never just copper. Usually, they're brass, which is an alloy of copper and zinc. The zinc is dissolved in the AP as well as the copper, but because it is more reactive than copper, it eventually displaces the copper and you are left with a zinc chloride solution instead of a copper chloride solution. That's what you saw when the solution turned clear.
You can probably process a pound of pins in two gallons of AP. I'm not sure because I don't process such quantities of pins. Others may be able to answer that better than I can. Just remember, there's not a lot of gold on partially plated pins, so you will eventually produce a lot of waste for a little gold. That waste must be properly treated before disposing of it, and that adds more cost.
As you said, with enough time and effort, you can learn to process most items, but now you have to think in terms of months and years. It took me about a year and a half to read through the entire forum, and that was a couple years ago. The forum continues to grow, so it would take me longer now.
Read Hoke's book. While it does not deal with eWaste, it will give you a sound foundation in dealing with precious metals. Study what has already been written on the forum. It's all here, but it will take a long time. While I'd like to help guide you and every other new member on your journey, we all have other responsibilities in our lives. Study the Safety section. Study how to deal with waste. We created a Library section that holds some of the best threads from the forum. Read, read, read. The longer you study, the more it will all start to make sense.
I wish you the best of luck,
Dave