Aqua Regia Problem please help

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http://www.gesswein.com/p-3263-refining-precious-metal-wastes.aspx?cpagenum=&sortfield=&sortdirection=&perpage=
 
butcher said:
necromancer,

I believe GSP was just trying to avoid some of the problems, and tone on the forum, (like the wolf pack mentality with new members...), with his comment the other day. To improve the forum, which I know is also what you wish to do here, to help members of the forum, and also help our new members get started learning.

Nobody kicked you. you are just perceiving, or receiving it wrong.


the "kick" was not taken personally, i understand (in retrospect) i was out of bounds, it was in no way perceived as doing me wrong !!

if you knew me in person you would see "trouble" is my middle name :oops:

i did send GSP a sorry in a private message.
 
lukeduke077 said:
Here is a pretty big question ? When you heat regia to a simmer. How far can those gases travel before they become mostly harmless ? I live in a town and have neighbors fairly close. Are they going to call the law on me because of the smell ? Do you need to live on some fairly open land to this without harressment ?
If your neighbors can smell the fumes, they can DIE because they smell the fumes :shock:

One question you need to correctly answer before you are ready to continue is ""where is your gold at this time"" :?:
As a hint it is probably Not where you think it is :shock:
 
lukeduke077 said:
Here is a pretty big question ? When you heat regia to a simmer. How far can those gases travel before they become mostly harmless ? I live in a town and have neighbors fairly close. Are they going to call the law on me because of the smell ? Do you need to live on some fairly open land to this without harressment ?

something to take into consideration:

1 how much is bail in your town?
2 how much do lawyers charge ?
3 if your neighbors get sick how much will the law suit be ??
4 what if your family gets sick or you get a big lung full of NOX
5 what are the hospital fees

a little something to think about !!!!!

how about this..... the neighborhood kids getting video of you having the police showing up at your door, arresting you & uploading it onto the internet.

you can play smart & build a ""scrubber""

but only after you learn about what your doing, save up your scrap it will not go anywhere, don't be in a rush

the faster you run the more it hurts when you trip.

read the first quote in my sig line
 
4metals said:
By the way, you read that book pretty quick. You first heard about the book at 11:30 last night and by 6:30 this morning you have read (and understood) the book? That much information doesn't sink in as fast as you seem to think it does.

Actually back in 2011 when I fist joined the forum one of the first things I did was download & read Hokes - & I did so in about 5 or 6 hours --- because I had already been playing around with recovery & refining for about 6 months --- (based for the most part on a lot of bad info found else where on the net) the info in here book sank in quite fast & well on that first read through --- in no way am I saying that first read through made me a refiner in that 5 or 6 hours - but it brought a lot of understanding to what I had already been playing with & cleared up a lot of the mis-information I had been working on - that first read through got me headed down the right path

I of course had to refer back to her book "often" in the beginning (& still do from time to time) & in no way do I consider myself a master refiner now after only 3 years of working at it &/or 3 years of being a member of this forum - I still have a lot to learn & do so most every day --- I am just saying the first time I read Hokes was like an eye opening light bulb "moment" & because I had already been playing with it - it was absorbed pretty good on the first read

Kurt
 
Greetings lukeduke077

Very important warning...
Gold fever is blinding!

You seem to be blinded as the rest of us have gone through.
Stop rushing to get the gold in hand. You will lose.

You have read alot and wrote about what you did and what you need to do. That's great, you are at least thinking but you are still rushing things.
What you wrote has many flaws and steps missing and steps mixed together and so on.

Give alittle time for things to sink in. Like how long ago Hoke's book was written and how things can change by time and other brain's adding information.

You've ordered alot of lab stuff you will probably never use and wasted $.
Most of the experiements can be done with stuff bought at a thrift store for very little.

Everyone has this "blindness". I had hundreds of lbs. of electronic scrap, bought a small booklet with alot on "poor man's AR". From start to finish it had almost all the steps nicely written. So within a week I dove in and had a system up and was running alot of circuit boards though and getting alot of "Solids" as end products. Everything looked great and running nicely. Every night after work, I'd spend an hour moving solutions and making new batches of AR, rinsing, "neutrilizing" and thought I had it down pat.

Then, 1 friday when I had to do a quick clean out as my now "X" wife told me they were taring down the garage Saturday morning, I came home early from work to find the garage all but gone!
The soon to be new owners got permission to remove it friday instead of saturday! Everything was "dumped" onto the ground and taken to the dump...

They had no clue what they did nor cared when I mentioned it...

Very tough lesson learned there.
Not only making sure the building was going to be there long enough to do what's planned. But also being definately sure every step is right and followed.

I was not "refinning" gold from scrap as planned out carefully.

I was merely making a major mess of mixing metals and acids into a dangerous blend of waste solution and solids.

The almost full beaker of what I "knew" was gold was washed away with more then 15 gallons of acidic water that still had alot of base metals dissolved, into the ground where there is now a blacktop parking area.

B.S.
...Please step back and absorb what you have "read" so that learning it can begin...
 
lukeduke077 said:
Here is a pretty big question ? When you heat regia to a simmer. How far can those gases travel before they become mostly harmless ? I live in a town and have neighbors fairly close. Are they going to call the law on me because of the smell ? Do you need to live on some fairly open land to this without harressment ?


Hello,
Look up "watchglass covers". Its simply a small pane of glass used to cover glass beakers while they are being used to consume base metals & while doing AR or anytime you need to pretty much confine fumes when working outside without the luxery of a fumehood & a scrubber to do the job of safety, it also keeps the working fumes working. Also add acids in small amounts never all at once, you should have no boil overs & minimual fuming to worry about then. Watch the heating process also, low at first then,.........just enough to keep things hot, don't boil, that makes dangerious vapors. Good idea is to to place a pyrex glass dish first on the hotplate, then place the beaker in it incase of a boil over etc... Stop everything you are doing & don't just read the safety posts MEMORIZE them then proceed. This is dangerious stuff & if you screw up & anyone does fall ill the EPA will crucify you as will everyone involved. A resperator of any type wont help so make sure you are upwind always period unless it supplys its own oxygen.

If your neighbors windows are open don't even consider doing anything if they are next door. Or if pets or children are about. The watchglass thing really lowers the gassing tho.

Read about the waste disposal issues, you will need to address that also first before proceeding, its as tedious process as refining if done properly.
Hope you are using a fan to blow or draw away all fumes.

Best of luck, Gold filled & rolled Gold etc.. is a lot different then regular carat Gold, solid Gold, or fingers to refine, Lots of odd base metals to have to contend with and you never really know what is in it till you test ea. pc to see what it is composed of. If you can sort similar items & do them alone that will help keep your acid soup a bit cleaner.

I had better luck melting mine down with a torch & making cornflakes as they call it in a metal bucket with very cold distilled water in it. The smaller pcs. are open to much easier acid consumption.


Dave
 
Hi panther :)
I have totally halted my process at this point. Last night I found hoke's book on the forum with revisions. I can not remember who posted it with some important revisions to processes. But I would surly like to thank you. There was a lot of new information for me to digest in the revisions.

Most of my supplies I ordered are chemicals, and melting supplies . I decided to hold off on the beakers and what not. I live near Oxford Ohio which is where Miami University is located. I sell antiques for a living. So you would be amazed at all the stuff I find. I have been involved in antiques since I was a child. I have great picking locations for material. However large barrels and things are hurting my head. I am not sure where to pursue these items.

I really just want the ability to process small batches of scrap. I get a lot of scrap gold fill because I sell antique jewelry & watches. My ideal volume would be about 8OZT or 240 grams at a time. I think if I could process that amount once a week. Within a few months I would have all my scrap processed. Thus leaving me a nice bit of gold. Which if a big deal came up. I could use to raise cash to purchase. I also need to start saving for my future. I would like to buy some rental properties in the future. I have no desire to die doing home refining. I kind of pride myself on not being a dumb ---.
I am not reckless. I have been sitting for 3 years studying this from a different angle. my teacher taught me how to buy scrap material at auctions. he also taught me how to buy gold & silver jewelry at scrap rates. I learned I could resell the nicer pieces for a premium. As I progressed in the field. I started to learn the types of margins bigger fish work on. I could not fathom scrap shops making only 1 percent on volume. So I decided I would start studying. I have not figured my answer out entirely yet. However I can tell there making a heck of a lot more then 1 percent.

Now I am starting to see the backside of the equation. Which my teacher is totally oblivious too. He tends to totally discount how much money is still left in his material. I think he is missing out a large amount of profit. Since I am much smaller it seems reasonable to me. To try and capture those lost profits. This old bloodhound thinks he has caught the scent :) So I would like to tree Mr. AU

After spending some time studying on here. A lot of the people have been very forceful about the dangers. I do appreciate them imploring how dangerous processing really is. They have done a great job. Plum made me nervous to push any further. Now I wonder if I am out of my league .

All this studying has just given me a 1000 more questions with possible answers.

When we made our batch. I had a strong early gas reaction. However after initial burn off solution only produced minimum gas. I looked into fume hoods. Good God they are pricey. I also thought about building a fume hood. That's going to cost just as much as a cheap manufactured model. I think you could trick out a made hood for increased performance. Yet either way your still sinking a lot of money.

I also looked at the scrubber options. Your going to spend less money. Yet your going to have lots of buckets killing grass. There also in my situation going to be visible to people .

I was going to ask about hoke's cake dish trick. Which I think will work for my small batches. Another person also mentioned a watch glass. I love that idea as I have a lot of clock crystals. Which are glass and I think would work. I do not mind to spend the money to be safe. If the operation is profitable to my bottom line. At this point it seems crazy to spend money on a scrubber or hood. I need to have a practical tangible results. My number one motive doing this was to measure some yields. I wanted to evaluate if it was more profitable for a little guy then selling to the refiners. my stock pile of 3 years was to be my test material. All of the material has been paid for and is now profit. I gathered this stuff buying stuff with the items that was resellable.

I now understand the 3 tanks for braking down the other metals from the solution. So that you get a clean PH7 water for disposal. I also understand why it is important to do those steps.

What I really need from the members . I guess is help to set a design model. Which is affordable and safe for me & my community. Where I can process some small batches to determine yields. Without the neighbors or there animals getting sick. No Lawyers trying to sue me. No Police trying to arrest me. No EPA trying to fine me for my next 20 years of earnings.

The revised Hoke's Book is the steps I would use for future batches. Not the steps I typed above based on the book from 1940. Since no one pointed that out to me :) That should convince some of you that I am indeed reading and studying the methods. The science is not scary to me ! I am excited to learn new processes and understand the why's of each reaction. I think that these enlightenments will carry over to other things not involved with processing materials. The science of applied sciences. The logistics and construction do worry me a little. However I think with a little constructive help. I can overcome this obstacle.

Dave I referenced the watch glass above. I also referenced the tanks I need to make for filtering the waste metals. My main question is what to do with the stuff that drops out. Can I dispose of the metals in the general trash after rinsing ? I was going to do my Nitric work early morning or late evening. Trying to use times when people are less active outside. In the future I do plan to make the shot pellets for consumption. I think that will save me a lot of acid as well. You all have done your job well. You have me in here studying and learning lol. I have not done any real work in the last 2 days. Because of all this studying & learning :) I realize I have a lot more to learn .
 
lukeduke077 said:
In the future I do plan to make the shot pellets for consumption. I think that will save me a lot of acid as well.

Gold filled is not run that way. That will cause you a whole new set of problems!
Gold filled is not something you really want to learn on first. There are so many problems that you will encounter as a newbie you will get frustrated and lose your gold from the lack of experience. To many variations and to many equations to take into account unless you have the experience that comes with processing and not just the knowledge side of it either. Gold filled is really easy, but only after you have done many a many processes will it seem that way. You would come out better having it refined for 10%-15% then doing it yourself IF it's not your full time business. Karat is a little different story.
 
Would I be better off to work on some e scrap or cell phone scrap . To start with first ? I have that kind of stuff laying around too.
 
There really are no refiners to my knowledge in my area. I have tried to find a company within a hour of my house. I think the nearest 1 is up near Columbus .
 
I would start with something easy like Karat scrap or fingers or pins. These will teach you the simple chemical reactions and processes you need to work complex chemical reactions which are sometimes complicated to say the least. Those processes are easier to control and recover from if you have a problem and will give you the hands on experience you need for the next step. First you learn how the gas and brakes work and then you can get a speeding ticket. :mrgreen:
 
Nice reply.
I'm glad you stopped to smell the pile that's in front of you.
Goto the section on where to find PMs. You might be very supprised at some of your Antiques.

You have the smarts to learn how to and devise a game plan. Antiques and gold buying are arts that take years to develope.

All the information is here in the forum so good luck and hope to see a nice shinny from you soon enough.

B.S.
... O yeh, Take a close look at all those gold trimmed glassware you been tossing into the trash cause there's so much of it...
 

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