Post video as proof cupeling works for you.. Anyone can say it works. If it becomes lead in the process then whats the difference if you use lead?
In addition to what Yggdrasil said, the Litharge is intimately mixed with the ore. This fine powder will turn into a virtual "rain" of Lead particles, when heated to around 1800 F. This allows better contact with the mostly very fine ( as in small ) Au particles, producing bigger alloy beads, which then have a better chance to settle in the crucible.
Using metallic Lead will turn it liquid at around 450 F., causing it to settle in the bottom before intimate Au particle contact. The only way then, is to swirl the hot liquid flux/ore mix, when it is at 2000 F. + degrees, to mix the Pb with the hot material, for a relatively good collection of the PMs. Not recommended, even in a solid concrete structure, wearing a fire proof suit.
Also, since an assay is performed at a temperature close to the melting point of the PM alloys, it is likely the contents of the crucible will freeze, if not poured almost immediately.
The assay business has adopted techniques developed over many 100s of years, and has used PbO as the go to collector, even in todays environmentally conscience world. Why? Because it works the best. Metallic Pb will work, to a degree, but I want my results to be as close to 100%. Especially when dealing with hard earned Au.